103793-64-2

Downstream Products

• 103793-65-3 (E)-(1R,4R,5R)-4,5-Bis-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-1-[(2R,3S,4R,5S,6R)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-2-yl]-hept-2-en-1-ol 
• 103793-65-3 (Z)-(1S,4R,5R)-4,5-Bis-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-1-[(2R,3S,4R,5S,6R)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-2-yl]-hept-2-en-1-ol 
• 103793-65-3 (Z)-(1R,4R,5R)-4,5-Bis-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-1-[(2R,3S,4R,5S,6R)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-2-yl]-hept-2-en-1-ol 
• 103793-65-3 (E)-(1S,4R,5R)-4,5-Bis-benzyloxy-7-(tert-butyl-diphenyl-silanyloxy)-1-[(2R,3S,4R,5S,6R)-3,4,5-tris-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-tetrahydro-pyran-2-yl]-hept-2-en-1-ol 

Relevant academic research and scientific papers

A PRACTICAL SYNTHESIS OF TRANS-IODOOLEFINS

Trimethylsilyl iodide was found to react smoothly with the acetylenic ketones 3 and 6 to yield the trans-β-iododovinyl ketones 4 and 7, respectively.Hydride reduction of 4 and 7 gave the trans-iodoolefins 5 and 8, which correspond to the C.19-C.22 and C.1