103811-99-0Relevant academic research and scientific papers
On the electrochemical fluorination of quaternary ammonium compounds. Part 1. Tetraalkyl ammonium salts
Dimitrov. A.,Radeck, W.,Ruediger, St.,Bechstein, O.
, p. 57 - 60 (1993)
Tetraalkylated ammonium compounds, which are known to be very stable towards oxidative attack, can be electrofluorinated readily to yield perfluoro tertiary amines.Other than the enhanced formation of gaseous cleavage products, the electrofluorination proceeds similarly to that of other tertiary amines.
The electrochemical fluorination of nitrogen-containing carboxylic acids. Fluorination of methyl esters of 3-dialkylamino propionic acids
Abe, Takashi,Hayashi, Eiji,Fukaya, Haruhiko,Hayakawa, Yoshio,Baba, Hajime,et al.
, p. 101 - 111 (2007/10/02)
Six methyl esters of 3-dialkylamino-substituted propionic acids were subjected to electrochemical fluorination to give the corresponding perfluoroacid fluorides.The following dialkylamino substituents were investigated: diethylamino, di-n-propylamino, di-n-butylamino, pyrrolidino, morpholino and piperidino groups.These perfluoroacid fluorides, which were obtained in fair yields, are considered to be prospective key precursors for preparing soft-type (degradable) fluorochemicals.The salts show a considerable lowering of surface tension in aqueous solution.Thephysical properties of all the perfluoroacid fluorides obtained are reported, together with their spectroscopic data (19F NMR, mass and IR spectra).
