1038399-83-5

Basic information

• Product Name: trimethyl (1E,3E)-1-[(benzyloxycarbonyl)amino]-4-(dimethylamino)buta-1,3-diene-1,2,3-tricarboxylate
• Synonyms: trimethyl (1E,3E)-1-[(benzyloxycarbonyl)amino]-4-(dimethylamino)buta-1,3-diene-1,2,3-tricarboxylate
• CAS NO: 1038399-83-5
• Molecular Weight: 420.419
• Mol File: 1038399-83-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trimethyl (1E,3E)-1-[(benzyloxycarbonyl)amino]-4-(dimethylamino)buta-1,3-diene-1,2,3-tricarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl (1E,3E)-1-[(benzyloxycarbonyl)amino]-4-(dimethylamino)buta-1,3-diene-1,2,3-tricarboxylate(1038399-83-5)
• EPA Substance Registry System: trimethyl (1E,3E)-1-[(benzyloxycarbonyl)amino]-4-(dimethylamino)buta-1,3-diene-1,2,3-tricarboxylate(1038399-83-5)

Safety Data

• Hazardous Substances Data: 1038399-83-5(Hazardous Substances Data)

Upstream product

• 762-42-5 dimethyl acetylenedicarboxylate 
• 219739-90-9 Methyl (Z)-2-<(benzyloxycarbonyl)amino>-3-dimethylaminopropenoate 

Relevant articles and documents

Regiospecific [2+2] cycloadditions of electron-poor acetylenes to (Z)-2-acylamino-3-dimethylaminopropenoates: synthesis of highly functionalised buta-1,3-dienes

Microwave-assisted [2+2] cycloaddition reactions of 2-amino-3-dimethylaminopropenoates with acetylenecarboxylates furnished highly functionalised 1-amino-4-(dimethylamino)buta-1,3-dienes in 40-94% yields. All reactions were observed to consistently produce single geometrical isomers, and in cases where non-symmetrical acetylenes were employed the reactions proceeded in a regiospecific manner.