103867-67-0

Basic information

• Product Name: (E)-5,6-Dimethyl-1-(toluene-4-sulfinyl)-hept-1-en-4-ol
• CAS NO: 103867-67-0
• Molecular Weight: 280.431
• Mol File: 103867-67-0.mol

Chemical Properties

• CAS DataBase Reference: (E)-5,6-Dimethyl-1-(toluene-4-sulfinyl)-hept-1-en-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-5,6-Dimethyl-1-(toluene-4-sulfinyl)-hept-1-en-4-ol(103867-67-0)
• EPA Substance Registry System: (E)-5,6-Dimethyl-1-(toluene-4-sulfinyl)-hept-1-en-4-ol(103867-67-0)

Safety Data

• Hazardous Substances Data: 103867-67-0(Hazardous Substances Data)

Upstream product

• 10381-71-2 p-tolyl allyl sulfoxide 
• 49642-48-0 2,3-dimethylbutanal 

Relevant articles and documents

STEREOSELECTIVE SYNTHESIS OF (E)-2-ALKENE-1,4-DIOLS VIA METALLATED ALLYLIC SULPHOXIDES

Reaction of allyl sulphinyl anion with chiral α-methylaldehydes affords α- or γ-adducts in highly regiocontrolled fashion, depending on reaction conditions.From the α-adducts syn (E)-2-alkene-1,4-diols are obtained as major (d.r. 2:1 28:1) products by thiophile promoted desulphurization.

Cram-selective Addition of α-Allyl Sulphinyl Anion to Chiral Aldehydes: Synthesis of (E)-1,4-Dihydroxyalk-2-enes

The stereoselective introduction of an allylic alcohol function into chiral aldehydes is readily achieved by sequential condensation of aldehydes with an allylic sulphinyl anion and thiophile-promoted desulphurization of the resulting α-substituted allylic sulphoxides.