1038932-52-3Relevant academic research and scientific papers
Three-dimensional shape-persistent fluorescent nanocages: Facile dynamic synthesis, photophysical properties and surface morphologies
Luo, Jia,Lei, Ting,Xu, Xiaoguang,Li, Fang-Mei,Ma, Yuguo,Wu, Kai,Pei, Jian
scheme or table, p. 3860 - 3865 (2009/06/05)
A study was conducted to investigate facile dynamic synthesis, photophysical properties, and surface morphologies of three-dimensional (3D) shape-persistent fluorescent nanocages. The 3D functionalized body was utilized to couple with suitable planar caps that enabled achieving quantitative formation of C3 symmetrical nanocages, with intensive visible luminescence through dynamic covalent chemistry (DCC). The study demonstrated that DCC has emerged as an efficient synthetic strategy, due to its error-checking and proof-reading features, generating thermodynamically controlled products through reversibility. The selective introduction of three conjugated arms generated fluorescent property and offered the interactions between elements involved in the synthesis process.
