103896-59-9

Basic information

• Product Name: 2-[1-Amino-1-phenyl-meth-(Z)-ylidene]-3-methylene-succinic acid dimethyl ester
• Synonyms: 2-[1-Amino-1-phenyl-meth-(Z)-ylidene]-3-methylene-succinic acid dimethyl ester
• CAS NO: 103896-59-9
• Molecular Weight: 261.277
• Mol File: 103896-59-9.mol

Chemical Properties

• CAS DataBase Reference: 2-[1-Amino-1-phenyl-meth-(Z)-ylidene]-3-methylene-succinic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[1-Amino-1-phenyl-meth-(Z)-ylidene]-3-methylene-succinic acid dimethyl ester(103896-59-9)
• EPA Substance Registry System: 2-[1-Amino-1-phenyl-meth-(Z)-ylidene]-3-methylene-succinic acid dimethyl ester(103896-59-9)

Safety Data

• Hazardous Substances Data: 103896-59-9(Hazardous Substances Data)

Upstream product

• 16717-64-9 1-azidostyrene 
• 103896-55-5 N-(1-Phenylvinylimino)triphenylphosphorane 
• 762-42-5 dimethyl acetylenedicarboxylate 

Relevant articles and documents

Reaction of (vinylimino)phosphoranes with electron-deficient acetylenes: Synthesis and reactivity of 1, 2λ5-azaphosphinines

The reactions of trimethoxy(1-phenylvinylimino)phosphorane and methoxydiphenyl(1-phenylvinylimino)phosphorane with electron-deficient acetylenes result in the formation of 1,2λ5 -azaphosphinines (7a,b) and (9a,b), while those of triphenyl(1-phe

ON THE REACTION OF N-VINYLIMINOPHOSPHORANES. SYNTHESIS AND REACTION OF 1,2-λ5-AZAPHOSPHORINE RING SYSTEM

The reaction of N-vinyliminotrimethoxyphosphorane reacts with electron deficient acetylenes results in the formation of formal cycloadducts, 1,2-λ5-azaphosphorines 4a-c.However, N-vinyliminotriphenylphosphorane reacts with dimethyl acetylenedicarboxylate (DMAD) in a formal manner.The product 4a or 4b also reacts with DMAD to give λ5-phosphorine derivatives.