10394-97-5Relevant academic research and scientific papers
Functional Group Interconversion of Alkylidenemalononitriles to Primary Alcohols by a Cooperative Redox Operation
Emmetiere, Fabien,Grenning, Alexander J.
, p. 3077 - 3085 (2020/08/10)
Functional group interconversions are essential chemical processes enabling synthesis. In this report, we describe a strategy to convert alkylidenemalononitriles into primary alcohols in one step. The reaction relies on a choreographed redox process invol
Deconjugative alkylation/Heck reaction as a simple platform for dihydronaphthalene synthesis
Navaratne, Primali V.,Grenning, Alexander J.
supporting information, p. 69 - 75 (2016/12/27)
A simple platform for carbocycle synthesis by Knoevenagel adduct deconjugative alkylation/Heck reaction is described. Deconjugative alkylation of Knoevenagels adducts is two-fold synthetically enabling because C-C bond formation is (1) operationally simple due to the ease of Knoevenagel adduct carbanion generation and (2) results in alkene migration, which poises the substrate for cyclization. Furthermore, the gem-dinitrile moiety serves as a functional group for synthetic manipulation.
Novel Dyestuffs Containing Dicyanomethylidene Groups
Katritzky, Alan R.,Fan, Wei-Qiang,Liang, De-Sheng,Li, Qiao-Ling
, p. 1541 - 1546 (2007/10/02)
Several series of novel compounds have been prepared containing dicyanomethylidene groups including 1-alkyl-3-dicyanomethylideneindol-2-ones and 6,6-dicyanofulvenes.Their visible absorption properties are recorded and discussed.
