1039557-09-9

Basic information

• Product Name: N,N-diethyl-2-(1H-indol-2-yl)benzamide
• Synonyms: N,N-diethyl-2-(1H-indol-2-yl)benzamide
• CAS NO: 1039557-09-9
• Molecular Weight: 292.381
• Mol File: 1039557-09-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-diethyl-2-(1H-indol-2-yl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diethyl-2-(1H-indol-2-yl)benzamide(1039557-09-9)
• EPA Substance Registry System: N,N-diethyl-2-(1H-indol-2-yl)benzamide(1039557-09-9)

Safety Data

• Hazardous Substances Data: 1039557-09-9(Hazardous Substances Data)

Upstream product

• 858647-69-5 N,N-diethyl-2-phenyl-1H-indole-1-carboxamide 

Downstream Products

• 1039557-11-3 tert-butyl 2-(2-(diethylcarbamoyl)phenyl)-1H-indole-1-carboxylate 

Relevant articles and documents

Anionic indole N-carbamoyl N → C translocation. A directed remote metalation route to 2-aryl- and 2-heteroarylindoles. Synthesis of benz[a]carbazoles and indeno[1,2-b]indoles

(Chemical Equation Presented) A new LDA-induced anionic N-C carbamoyl migration of 2-arylindoles (7) is reported. Treatment of N-carbamoylindoles 10 and 13, readily available by direct and ipso-borodesilylative Suzuki-Miyaura cross-coupling routes from 8 and 12, respectively, provides a general route to functionalized 2-arylindoles 11 and 14, respectively (Tables 1 and 2). The reaction has been applied to the synthesis of benzo[a]carbazoles 16 and indeno[1,2-b]indoles 18, and its intramolecularity has been established by a crossover experiment (Scheme 4).