1039627-07-0

Upstream product

• 781-06-6 (E)-pent-3-en-1-yl 4-methylbenzenesulfonate 
• 100-46-9 benzylamine 
• 1617-32-9 (E)-3-pentenoic acid 
• 764-37-4 (E)-3-penten-1-ol 

Downstream Products

• 448957-53-7 N-benzyl-4-hydroxypentylamine 
• 252353-57-4 1-benzylamino-pentan-3-ol 

Relevant academic research and scientific papers

A mechanistic alternative for the intramolecular hydroboration of homoallylic amine and phosphine borane complexes

Intramolecular hydroboration is demonstrated starting from homoallylic amine boranes upon activation by iodine. The process involves a B-iodoborane complex as the intermediate and may occur via internal displacement of iodide by the alkene to generate a cationic borane-alkene π-complex on the way to hydroboration products. The reaction can be carried out using a catalytic amount of iodine. Copyright

Aza-Wittig Rearrangements and Cyclizations by Transmetallation of N-Benzylaminomethylstannanes

Transmetallation of N-allyl-N-benzylaminomethylstannanes with butyllithium or methyllithium allows carbon-carbon bond formation by a -rearrangement.Substantial amounts of the protodestannylated product are also produced.Transmetallation of the corresponding α-methyl substituted allylic amine or homoallylic amine gives an overall rearrangement by cyclization onto the olefin followed by recapture of the new carbanion by tetramethyltin.