1039629-96-3Relevant academic research and scientific papers
An exceptional palladium-catalyzed alkenylation of silyl enol ether in the absence of a fluoride additive
Shigehisa, Hiroki,Jikihara, Takaaki,Takizawa, Osamu,Nagase, Hiromasa,Honda, Toshio
, p. 3983 - 3986 (2008/09/20)
An exceptional intramolecular palladium-catalyzed alkenylation of silyl enol ether in the absence of a fluoride additive was developed, and this reaction led to the construction of bicyclo[3.3.1]nonane ring system in reasonable yield. In this type of reactions, trialkylamines were employed as additives instead of previously indispensable fluoride additives.
