1039677-68-3Relevant academic research and scientific papers
Mechanistic study on the base-promoted reaction of allylphenylsilanes to alkenylsilanols
Imazeki, Shigeaki,Sugawara, Hiroo,Sano, Atsunori,Akiyama, Takahiko
body text, p. 623 - 629 (2009/04/11)
On treatment of allylphenylsilanes with t-BuOK and 18-crown-6 in DMSO, isomerization of the olefinic double bond and subsequent substitution of the phenyl group with a hydroxy group took place smoothly to afford alkenylsilanol derivatives in good yields. The reaction mechanism was investigated using 18O-labeled sulfoxide. We found that a (methylsulfinyl)methyl anion generated from DMSO participated in this reaction.
