1039775-68-2Relevant academic research and scientific papers
Active template synthesis of rotaxanes and molecular shuttles with switchable dynamics by four-component PdII-promoted Michael additions
Goldup, Stephen M.,Leigh, David A.,Lusby, Paul J.,McBurney, Roy T.,Slawin, Alexandra M. Z.
supporting information; experimental part, p. 3381 - 3384 (2009/02/07)
(Chemical Equation). Taking the Michael: Rotaxanes (see structure) and molecular shuttles are prepared in up to 99% yield by successive Pd II-promoted 1,4-conjugate additions in a one-pot four-component assembly process. This process represents the first active template reaction in which the template motif is retained in the interlocked product.
