103979-82-4

Basic information

• Product Name: (S)-7-Hydroxymethyl-7-phenylsulfanyl-hexahydro-pyrrolizin-3-one
• CAS NO: 103979-82-4
• Molecular Weight: 263.36
• Mol File: 103979-82-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-7-Hydroxymethyl-7-phenylsulfanyl-hexahydro-pyrrolizin-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-7-Hydroxymethyl-7-phenylsulfanyl-hexahydro-pyrrolizin-3-one(103979-82-4)
• EPA Substance Registry System: (S)-7-Hydroxymethyl-7-phenylsulfanyl-hexahydro-pyrrolizin-3-one(103979-82-4)

Safety Data

• Hazardous Substances Data: 103979-82-4(Hazardous Substances Data)

Upstream product

• 28833-81-0 2-(2,5-dioxopyrrolidin-1-yl)ethyl acetate 
• 122695-55-0 Acetic acid 2-(2-hydroxy-5-oxo-pyrrolidin-1-yl)-ethyl ester 
• 122695-46-9 1-(2-acetoxyethyl)-5-acetoxy-2-pyrrolidinone 
• 18190-44-8 1-(2-Hydroxy-ethyl)-pyrrolidine-2,5-dione 
• 122695-51-6 (S)-5-Oxo-1-phenylsulfanyl-hexahydro-pyrrolizine-1-carboxylic acid methyl ester 

Downstream Products

• 17958-41-7 (+)-supinidine 
• 551-59-7 (-)-supinidine 

Relevant articles and documents

NEW CHIRAL RECOGNITION OF CHIRAL TIN(II) ENOLATES TOWARD CYCLIC ACYL IMINIUM SPECIES. ASYMMETRIC TOTAL SYNTHESIS OF (-)-SUPINIDINE

Diastereoselective alkylation of chiral tin(II) enolates 1 onto cyclic acyl iminium ion 7 proceeded in a different chiral recognition mode from the case of 1 onto cyclic acyl imines 3.This new diastereoselective alkylation was efficiently utilized for an asymmetric total synthesis of (-)-supinidine (20).