1040140-83-7

Basic information

• Product Name: (1S,4S)-5-oxobicyclo[2.2.1]hept-2-en-2-yl diphenyl phosphate
• Synonyms: (1S,4S)-5-oxobicyclo[2.2.1]hept-2-en-2-yl diphenyl phosphate
• CAS NO: 1040140-83-7
• Molecular Weight: 356.315
• Mol File: 1040140-83-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1S,4S)-5-oxobicyclo[2.2.1]hept-2-en-2-yl diphenyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,4S)-5-oxobicyclo[2.2.1]hept-2-en-2-yl diphenyl phosphate(1040140-83-7)
• EPA Substance Registry System: (1S,4S)-5-oxobicyclo[2.2.1]hept-2-en-2-yl diphenyl phosphate(1040140-83-7)

Safety Data

• Hazardous Substances Data: 1040140-83-7(Hazardous Substances Data)

Upstream product

• 145092-68-8 (S,S)-bicyclo<2.2.1>heptane-2,5-dione 
• 2524-64-3 chlorophosphoric acid diphenyl ester 

Relevant articles and documents

Asymmetric synthesis of a chiral buckybowl, trimethylsumanene

The first asymmetric synthesis of a chiral buckybowl, a C3 symmetric (C)-8,13,18-trimethylsumanene (1), was achieved by employing a synthetic strategy that translates chirality at sp3 centers into bowl chirality. The synthesis features a syn selective cyclotrimerization of an enantiopure halonorbornene derivative, tandem ring-opening/closing olefin metathesis reactions, and DDQ oxidation at low temperature. The bowl-to-bowl inversion energy of 1 was determined as 21.6 kcal/mol by circular dichroism spectra measurement. Copyright