104016-73-1Relevant academic research and scientific papers
Lewis Acid Mediated Claisen-Type Rearrangement of Aryl Dienyl Ethers
Maruyama, Kazuhiro,Nagai, Naoshi,Naruta, Yoshinori
, p. 5083 - 5092 (2007/10/02)
Rearrangement of aryl pentadienyl ethers in the presence of BF3*OEt2 affords pentadienyl phenols in good yields without formation of the corresponding rearranged products.The mechanism of this rearrangement was studied by deuterium labeling and cross-coupling reactions.The scope and limitations of the rearrangement are discussed.
LEWIS ACID MEDIATED CLAISEN-TYPE REARRANGEMENT OF ARYL DIENYL ETHERS
Maruyama, Kazuhiro,Nagai, Naoshi,Naruta, Yoshinori
, p. 5149 - 5152 (2007/10/02)
In the presence of BF3.OEt2 aryl dienyl ethers were rearranged under mild conditions to afford dienyl phenols in good yields.
