1040264-44-5Relevant academic research and scientific papers
Rh(I)-catalyzed reaction of 2-(chloromethyl)phenylboronic acids and alkynes leading to indenes
Miyamoto, Masaki,Harada, Yasuyuki,Tobisu, Mamoru,Chatani, Naoto
supporting information; experimental part, p. 2975 - 2978 (2009/04/18)
(Chemical Equation Presented) The reaction of 2-(chloromethyl)phenylboronic acid (1) with alkynes in the presence of a Rh(I) complex gave indene derivatives in high yields. The regioselectivity depends on the steric nature of the substituent on the alkynes. A bulky group favors the α-position of indenes.
