104037-26-5

Basic information

• Product Name: 1-(2-(allyloxy)phenyl)ethanol
• Synonyms: 1-(2-(allyloxy)phenyl)ethanol
• CAS NO: 104037-26-5
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• EINECS: -0
• Mol File: 104037-26-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(2-(allyloxy)phenyl)ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-(allyloxy)phenyl)ethanol(104037-26-5)
• EPA Substance Registry System: 1-(2-(allyloxy)phenyl)ethanol(104037-26-5)

Safety Data

• Hazardous Substances Data: 104037-26-5(Hazardous Substances Data)

Usage

General Description

1-(2-(allyloxy)phenyl)ethanol, also known as allylphenylethanol, is a colorless liquid used in the production of fragrances and flavors. Its chemical structure consists of a benzene ring with an allyloxy group and an ethyl group attached. 1-(2-(allyloxy)phenyl)ethanol is commonly found in various natural products such as flowers and essential oils. It is known for its pleasant, floral-like odor and is frequently used as a perfume ingredient. Allylphenylethanol is also used in the synthesis of pharmaceuticals and other organic compounds due to its ability to enhance the aroma and taste of products. Overall, this chemical plays a significant role in the fragrance and flavor industry and is a versatile compound with various applications.

Upstream product

• 28752-82-1 2-(allyloxy)benzaldehyde 
• 917-64-6 methyl magnesium iodide 
• 90-02-8 salicylaldehyde 
• 74-88-4 methyl iodide 
• 53327-14-3 2'-allyloxyacetophenone 

Relevant articles and documents

Observations concerning the synthesis of heteroatom-containing 9-membered benzo-fused rings by ring-closing metathesis

A set of benzo-fused dienes with a 1,9-relationship and containing a variety of nitrogen and oxygen heteroatoms was readily synthesized. These dienes were then treated with the Grubbs second generation catalyst with the aim of synthesizing the 9-membered benzannelated heterocycles containing two heteroatoms (either O,O, NR,NR or O,NR where R = Ts or Boc). As previously observed in the literature, many of the dienes did not give the expected ring-closed product. However, a number of the desired products did form, namely with the 1,2-dihydrobenzo[c][1,5]oxazonin-7(5H)-one, 5,7-dihydrobenzo[b][1,5]oxazonine-6(2H)-carboxylate and 2,5,6,7-tetrahydrobenzo[b][1,5]oxazonine cores, albeit in poor yields. Rather surprisingly, the N-allyl-N-(2-(N-allyl-4-methylphenylsulfonamido)benzyl)-4-methylbenzenesulfonamide scaffold gave the desired ring-closed 1,6-ditosyl-2,5,6,7-tetrahydro-1H-benzo[b][1,5]diazonine in a high yield. Furthermore, when treated with the catalyst [RuClH(CO)(PPh3)3] the alkene isomerized into conjugation only with the benzylic NTs group and not with the phenyl NTs group to afford the 1,6-ditosyl-2,3,6,7-tetrahydro-1H-benzo[b][1,5]diazonine structure.

1,3-Dipolar Cycloadditions of Nitrones Derived from the Reaction of Acetylenes with Hydroxylamines

A study of the reaction of hydroxylamines with a variety of acetylenes has been carried out.Methylhydroxylamine readily reacts with methyl propiolate to give methyl 4-carbomethoxy-2-methyl-4-isoxazolidine-3-acetate.Further heating of this material results