1040379-06-3Relevant academic research and scientific papers
Highly regioselective isomerization - Hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands
Yu, Shichao,Chie, Yu-Ming,Guan, Zheng-Hui,Zhang, Xumu
supporting information; scheme or table, p. 3469 - 3472 (2009/05/07)
(Figure Presented) A series of new pyrrole-based tetraphosphorus ligands were synthesized and used for Rh-catalyzed isomerization-hydroformylation of internal olefins. It was found that the substituents at the 3,3′,5, 5′-positions of the biphenyl greatly effected the linear selectivity, and the alkyl-substituted tetraphosphorus ligands gave the best results (for 2-octene, n:i up to 207, for 2-hexene, n:i up to 362).
