104041-60-3Relevant academic research and scientific papers
Improved Catalytic Activity of Cyclopentadienylcobalt in the Preparation of Pyridines from Acetylenes and Nitriles
Wakatsuki, Yasuo,Yamazaki, Hiroshi
, p. 2715 - 2716 (2007/10/02)
The catalytic activity of cyclopentadienylcobalt increases greatly upon introducing a methoxycarbonyl group into the cyclopentadienyl ring, and by carrying out the reaction with a rigorous exclusion of oxygen.Among the precursors we have examined, the most active one was z)(cot)> (Cpz = methoxycarbonyl-substituted cyclopentadienyl; cot = cyclooctatetraene) which can generate the active species at 100 deg C.
