104065-67-0

Basic information

• Product Name: METHYL 3-METHOXY-2-PENTENOATE
• Synonyms: METHYL 3-METHOXYPENTE-2-NOATE;METHYL 3-METHOXY-2-PENTENOATE;IRRQVKLYAFXAKM-WAYWQWQTSA-N
• CAS NO: 104065-67-0
• Molecular Formula: C₇H₁₂O₃
• Molecular Weight: 144.17
• Product Categories: pharmacetical
• Mol File: 104065-67-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 188.6°Cat760mmHg
• Flash Point: 69.3°C
• Appearance: /
• Density: 0.978g/cm³
• Vapor Pressure: 0.595mmHg at 25°C
• Refractive Index: 1.427
• CAS DataBase Reference: METHYL 3-METHOXY-2-PENTENOATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 3-METHOXY-2-PENTENOATE(104065-67-0)
• EPA Substance Registry System: METHYL 3-METHOXY-2-PENTENOATE(104065-67-0)

Safety Data

• Hazardous Substances Data: 104065-67-0(Hazardous Substances Data)

Usage

Uses

3-Methoxy-2-pentenoic Acid Methyl Ester is an intermediate in the synthesis of prostaglandins.

InChI:InChI=1/C7H12O3/c1-4-6(9-2)5-7(8)10-3/h5H,4H2,1-3H3/b6-5+

Upstream product

• 30414-53-0 methyl propanoyl acetate 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 1526920-72-8 (2'R,3'R)-1-benzyl-5-bromo-4'-methoxy-3'-methylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-69-3 (2'R,3'R)-1-benzyl-5-fluoro-4'-methoxy-3'-methylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-70-6 (2'R,3'R)-1-benzyl-5-chloro-4'-methoxy-3'-methylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-71-7 (2'R,3'R)-1-benzyl-4-bromo-4'-methoxy-3'-methylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-73-9 (2'R,3'R)-1-benzyl-6-bromo-4'-methoxy-3'-methylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-74-0 (2'R,3'R)-1-benzyl-5-iodo-4'-methoxy-3'-methylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-75-1 (2'R,3'R)-1-benzyl-4'-methoxy-3',5-dimethylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-76-2 (2'R,3'R)-1-benzyl-4'-methoxy-3',7-dimethylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-77-3 (2'R,3'R)-1-benzyl-4'-methoxy-3',5,7-trimethylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-78-4 (2'R,3'R)-1-benzyl-4',5-dimethoxy-3'-methylspiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-79-5 (2'R,3'R)-1-benzyl-4'-methoxy-3'-methyl-7-(trifluoromethyl)spiro[indoline-3,2'-pyran]-2,6'(3'H)-dione 
• 1526920-80-8 1-benzyl-4'-methoxy-3'-methyl-6,7,8,9-tetrahydrospiro[benzo[g]indole-3,2'-pyran]-2,6'(1H,3'H)-dione 
• 135873-13-1 1-Ethyl-1,3,4,9-tetrahydro-6-(phenylmethoxy)pyrano[3,4-b]indole-1-acetic acid methyl ester 

Relevant articles and documents

Magnesium(ii)-catalyzed asymmetric hetero-Diels-Alder reaction of Brassard's dienes with isatins

The first catalytic asymmetric hetero-Diels-Alder reaction of Brassard's dienes with isatins was realized using Mg(ii)/N,N′-dioxide complexes as catalysts, affording the corresponding chiral spirolactones bearing tetrasubstituted centers in up to 99% yield with up to 99% ee and >99:1 dr within 3 hours. In the mechanism, based on the operando IR experiments, a predominant Diels-Alder pathway was found in the reaction. A possible transition state model was also proposed. This journal is