104086-68-2Relevant academic research and scientific papers
Selective aerobic oxidation of alcohols to aldehydes, carboxylic acids, and imines catalyzed by a Ag-NHC complex
Han, Lei,Xing, Ping,Jiang, Biao
, p. 3428 - 3431 (2014)
Silver NHC catalysts have been developed for the selective oxidation of alcohols to aldehydes or carboxylic acids in the presence of BnMe3NOH or KOH under dry air. The aerobic oxidation conditions are mild, and the yield is excellent. Further tandem catalysis enables the one-pot synthesis of imines in excellent yield. Only 0.1 mol % of the catalyst is required.
α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines
Rigoli, Jared W.,Moyer, Sara A.,Pearce, Simon D.,Schomaker, Jennifer M.
supporting information; experimental part, p. 1746 - 1749 (2012/04/23)
A convenient synthesis of α,β-unsaturated imines requiring only an allylic alcohol, an amine and a Ru catalyst has been developed. The use of large excesses of oxidant and the purification of sensitive intermediates can be avoided.
FLUORINATED ANALOGUES OF THE IMIDAZOLE INSECT GROWTH REGULATOR KK-42
Arbones, Cesar,Sanchez, Francisco J.,Marco, Maria-Pilar,Camps, Francisco,Messeguer, Angel
, p. 67 - 78 (2007/10/02)
The preparation of compounds 1b, 1c, and 1e, monofluoro and trifluoromethyl analogues of the imidazole KK-42 (1a) is reported.The synthetic sequence involves the formation of an imine between the appropriate fluoro aldehyde and benzylamine, followed by co
