104086-74-0Relevant academic research and scientific papers
Total Synthesis of the Labdane Diterpenes Galanal A and B from Geraniol
Lin, Shih-Che,Chein, Rong-Jie
, p. 1575 - 1583 (2017/02/10)
The first total synthesis of galanal A and B has been achieved from naturally occurring geraniol. Key steps in this synthesis are the use of a Lewis acid assisted chiral Br?nsted acid (chiral LBA) mediated cationic polyene cyclization and a titanocene-mediated radical cyclization for the asymmetric assembly of the "AB" ring and the construction of the all-carbon quaternary center at the junction of the "BC" ring, respectively.
Synthesis of labdane diterpenes galanal A and B from (+)-sclareolide
Kumar, Chebolu Naga Sesha Sai Pavan,Chein, Rong-Jie
supporting information, p. 2990 - 2992 (2014/06/23)
The first chemical synthesis of galanal A and B was achieved by a concise and highly efficient pathway starting from commercially available (+)-sclareolide and features a Wittig reaction and a titanocene-mediated radical cyclization as the key steps.
