1041199-44-3Relevant academic research and scientific papers
1,2,3-Triazole-linked dendrimers as a support for functionalized and recoverable catalysts for asymmetric borane reduction of prochiral ketones
Niu, Yan-Ning,Yan, Ze-Yi,Li, Gao-Qiang,Wei, Hai-Long,Gao, Guo-Lin,Wu, Lu-Yong,Liang, Yong-Min
, p. 912 - 920 (2008/09/21)
A series of new, functionalized, and chiral catalysts have been synthesized based on 1,2,3-triazole-linked dendrimers. It has been found that dendrimer 7f is an efficient catalyst for the enantioselective borane reduction of both electron-deficient and electron-rich ketones, and high enantioselectivities were obtained (up to 96%). The catalyst can be recovered and reused four times without a significant loss of catalytic activity.
