104128-34-9Relevant academic research and scientific papers
Structural Studies on 9-Hydrazono-6,7,8,9-tetrahydro-4-oxo-4H-pyridopyrimidines by 1H, 13C and 15N NMR Spectroscopy
Toth, Gabor,Szoelloesy, Aron,Almasy, Attila,Podanyi, Benjamin,Hermecz, Istvan,et al.
, p. 687 - 693 (2007/10/02)
1H, 13C and 15N NMR studies demonstrated that 9-hydrazono-6,7,8,9-tetrahydro-4-oxo-4H-pyrido-pyrimidines exist as an equilibrium mixture of Z-E isomers in the hydrazono-imino tautomeric form having an exocyclic double bond.Proton-catalysed Z-E interconversion is fast.Substituent and solvent effects revealed that the decisive factors controlling the Z:E ratio are internal hydrogen bonding in the Z-isomer, stabilization and steric interaction.
