1041307-85-0Relevant academic research and scientific papers
Nucleophilic substitution reaction at an sp2 carbon of vinyl halides with an intramolecular thiol moiety: synthesis of thio-heterocycles
Lei, Mao-Yi,Xiao, Yong-Jun,Liu, Wei-Min,Fukamizu, Koji,Chiba, Shunsuke,Ando, Kaori,Narasaka, Koichi
experimental part, p. 6888 - 6902 (2009/12/06)
This article presents a full account of intramolecular vinylic substitution reactions of bromoalkenes having an acetylthio moiety, which give sulfur-containing heterocycles such as dihydrothiophene, tetrahydrothiopyran, and 2-alkylidenethietane derivative
"Ligand-free" CuI-catalyzed highly efficient intramolecular S-vinylation of thiols with vinyl chlorides and bromides
Zhao, Qiwu,Li, Ling,Fang, Yewen,Sun, Deqian,Li, Chaozhong
supporting information; experimental part, p. 459 - 462 (2009/04/07)
(Chemical Equation Presented) With CuI as the catalyst and K 3PO4·3H2O as the base, highly efficient intramolecular S-vinylation of thiols with vinyl chlorides or bromides was successfully implemented without the help of a
Nucleophilic substitution at an sp2 carbon of vinyl halides with an intramolecular thiolate moiety: synthesis of 2-alkylidenethietanes
Lei, Mao-Yi,Fukamizu, Koji,Xiao, Yong-Jun,Liu, Wei-Min,Twiddy, Scott,Chiba, Shunsuke,Ando, Kaori,Narasaka, Koichi
, p. 4125 - 4129 (2008/09/21)
Various 2-alkylidenethietanes were synthesized by intramolecular nucleophilic substitution reactions at an sp2 carbon of vinyl halides with thiolate moieties. The reaction pathway of the substitution reactions was confirmed as a very rare Ssub
