1041346-08-0Relevant articles and documents
A PhSeCl-mediated allylic oxidation of prenyl moiety: A convenient method for the construction of 3-isopenten-2-ol unit
Oshida, Motoko,Nakamura, Tomoaki,Nakazaki, Atsuo,Kobayashi, Susumu
, p. 404 - 406 (2008)
A phenylselenenyl chloride (PhSeCl)-mediated allylic oxidation to give allylically rearranged alcohol has been developed. A possible mechanism for the present reaction is generation of allylic selenide from prenyl moiety via [1,3]-sigmatropic rearrangement, followed by oxidation and [2,3]-sigmatropic rearrangement to afford 3-isopenten-2-ol.