104142-11-2Relevant academic research and scientific papers
Free Radical Reactions of 1,1-Diarylethylenes with t-Butylmercury Chloride
Russell, Glen A.,Khanna, Rajive K.,Guo, Deliang
, p. 632 - 634 (2007/10/02)
The photostimulated reactions of Bu(t)HgCl with 1,1-diarylethylenes yield different products for the aryl groups C6H5, p-O2NC6H4, or p-MeOC6H4 reflecting the donor or acceptor properties of Bu(t)CB2C(*)(Ar)2.
Free Radical Reactions of Organomercury Halides with Alkenes and Alkynes
Russell, Glen A.,Jiang, Wan,Hu, Shui Sheng,Khanna, Rajive K.
, p. 5498 - 5499 (2007/10/02)
Substituted acetylenes or electronegatively monosubstituted ethylenes react with t-BuHgCl in photostimulated free radical chain processes in PhH or Me2SO to form R1C(t-Bu)+C(HgCl)R2 (R1, R2 = H, Ph; H, COMe; EtO2C, Ph; EtO2C, EtO2C) or t-BuCH2CH(HgCl)E (E
THE-PALLADIUM-CATALYSED REDUCTIVE ADDITION OF ARYL IODIDES TO PROPARGYL ALCOHOLS: A ROUTE TO γ,γ-DIARYL ALLYLIC ALCOHOLS
Arcadi, A.,Cacchi, S.,Marinelli, F.
, p. 5121 - 5132 (2007/10/02)
The reaction of aryl iodides with ethynyl and arylethynyl, dialkyl carbinols in the presence of the tri- or dialkylammonium formate-palladium reagent provides a convenient route to γ,γ-diarylallylic alcohols.In the presence of arylethynyl, alkylcarbinols a lack of regioselectivity was observed and mixtures of β,γ-, γ,γ-diarylallylic alcohols, and α,β-unsaturated ketones were obtained.
