1041509-23-2Relevant articles and documents
NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines
Castro, Luis C. Misal,Sortais, Jean-Baptiste,Darcel, Christophe
, p. 151 - 153 (2012)
A general and efficient hydrosilylation of imines catalysed by a well defined NHC-carbene cyclopentadienyl iron complex has been developed. Both aldimines and ketimines are converted to the corresponding amines under mild conditions, and under visible light activation.
Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines
Bheeter, Linus P.,Henrion, Mickael,Chetcuti, Michael J.,Darcel, Christophe,Ritleng, Vincent,Sortais, Jean-Baptiste
, p. 3111 - 3116 (2013/12/04)
The in situ generated nickel hydride complex, [Ni(Mes2NHC)HCp], and its cationic analogue, [Ni(Mes2NHC)(NCMe)Cp](PF6), are efficient and chemoselective pre-catalysts for the hydrosilylation of both aldimines and ketimines under mild conditions. The Royal Society of Chemistry.
Amine synthesis through mild catalytic hydrosilylation of imines using polymethylhydroxysiloxane and [RuCl2(arene)]2 catalysts
Li, Bin,Sortais, Jean-Baptiste,Darcel, Christophe,Dixneuf, Pierre H.
experimental part, p. 396 - 399 (2012/06/01)
Tolerate silicone! The stable [RuCl2(p-cymene]2 complex is an efficient catalyst for the direct chemoselective hydrosilylation of functionalized aldimines and ketimines into amines, using polymethylhydroxysiloxane as an inexpensive, stable, and safe hydrosilane source. The catalysis operates in ethanol, under air at room temperature, and tolerates the ketone ester and alkene functionality. Copyright