104170-04-9

Basic information

• Product Name: 3-Phenyl-but-3-enethioic acid S-ethyl ester
• CAS NO: 104170-04-9
• Molecular Weight: 206.309
• Mol File: 104170-04-9.mol

Chemical Properties

• CAS DataBase Reference: 3-Phenyl-but-3-enethioic acid S-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Phenyl-but-3-enethioic acid S-ethyl ester(104170-04-9)
• EPA Substance Registry System: 3-Phenyl-but-3-enethioic acid S-ethyl ester(104170-04-9)

Safety Data

• Hazardous Substances Data: 104170-04-9(Hazardous Substances Data)

Upstream product

• 104170-00-5 2-(ethylthio)carbonyl-2-methylphenetyl bromide 

Relevant articles and documents

The effect of cobalt(II) complex on the reactivity of thioester in radical process

The 1,2-rearrangement of an (alkylthio)carbonyl group and the radical substitution on sulfur are stimulated by the coexisting cobalt(II) complex, generated intermolecularly or intramoleculary.

RADICAL REARRANGEMENT OF A THIOESTER MEDIATED BY COBALAMIN

Zinc-reduction of 2-(ethylthio)carbonyl-2-phenylpropyl bromide in the presence of cobalamin gave the products formed by the migration of the thioester group.The formation of olefinic products excludes an anion mechanism and the rearrengement is concluded