104170-05-0Relevant academic research and scientific papers
Radico-catalysis: Possible involvement of a cobalt(II) complex in the free radical reactions of sulfur functions
Tada, Masaru
, p. 204 - 208 (2007/10/03)
A cobalt(II) complex is paramagnetic and can be coordinated with sulfur functions; the coordination complex delocalizes an unpaired electron from cobalt(II) to the sulfur functions such as thioester and vinyl sulfide. Thus, the generation of partial unpaired electron density on the sulfur functions induces or modifies the reactions of the organo free radical containing the sulfur function.
The effect of cobalt(II) complex on the reactivity of thioester in radical process
Tada, Masaru,Kaneko, Katsuyuki
, p. 843 - 844 (2007/10/03)
The 1,2-rearrangement of an (alkylthio)carbonyl group and the radical substitution on sulfur are stimulated by the coexisting cobalt(II) complex, generated intermolecularly or intramoleculary.
