104175-10-2Relevant academic research and scientific papers
Highly enantioselective and anti -diastereoselective catalytic intermolecular glyoxylate-ene reactions: Effect of the geometrical isomers of alkenes
Zhang, Xiang,Wang, Min,Ding, Ran,Xu, Yun-He,Loh, Teck-Peng
, p. 2736 - 2739 (2015)
An efficient method for the synthesis of homoallylic alcohols with high enantioselectivities and anti-diastereoselectivities via an In(III)-catalyzed intermolecular glyoxylate-ene reaction has been developed. The geometrical isomers of alkenes were shown to have different reactivities. Only the isomers of the alkenes having a proton β-cis to the substituent reacted in this catalytic system.
