1041751-59-0

Basic information

• Product Name: methyl (2R)-2-[(diphenylphosphoryl)(methyl)amino]-2-phenylethanoate
• Synonyms: methyl (2R)-2-[(diphenylphosphoryl)(methyl)amino]-2-phenylethanoate
• CAS NO: 1041751-59-0
• Molecular Weight: 379.395
• Mol File: 1041751-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (2R)-2-[(diphenylphosphoryl)(methyl)amino]-2-phenylethanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2R)-2-[(diphenylphosphoryl)(methyl)amino]-2-phenylethanoate(1041751-59-0)
• EPA Substance Registry System: methyl (2R)-2-[(diphenylphosphoryl)(methyl)amino]-2-phenylethanoate(1041751-59-0)

Safety Data

• Hazardous Substances Data: 1041751-59-0(Hazardous Substances Data)

Upstream product

• 62369-76-0 P-diphenyl(N-benzyl-N-methyl)-λ⁵-phosphinamide 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1499-21-4 Diphenylphosphinic chloride 

Relevant articles and documents

Asymmetric deprotonation-substitution of N-Pop-benzylamines using [RLi/(-)-sparteine]. Enantioselective sequential reactions and synthesis of N-heterocycles

(Chemical Equation Presented) Pop-directed asymmetric deprotonation of benzylic amines using [n-BuLi/(-)-sparteine] provides an efficient method for the synthesis of chiral NCα and NC α,α′ derivatives with total selectivity with respect to competing allylic and ortho lithiation. The method described herein offers a straightforward route of accessing chiral N-Pop-protected nitrogen heterocycles.