104185-17-3Relevant academic research and scientific papers
The Preparation and Characterisation of (Disulphur dinitrido)bis(phosphine) Complexes, (M=Pt, PR3=PMe3, PMe2Ph, PMePh2, PPh3, PEt3, PPrn3, PBun3, or 1/2Ph2PCH2CH2PPh2; M=Pd, PR3=1/2Ph2PCH2CH2PPh2). X-Ray Crystal Struc
Bates, Paul A.,Hursthouse, Michael B.,Kelly, Paul F.,Woollins, Derek J.
, p. 2367 - 2370 (1986)
Reaction of Na(S3N3) with (M=Pt, PR3=PMe3, PMe2Ph, PMePh2, PPh3, PEt3, PPrn3, PBun3, or 1/2Ph2PCH2CH2PPh2; M=Pd, PR3=1/2Ph2PCH2CH2PPh2) gives complexes of the type in high yield (quantitatively by 31P n.m
Preparation and Characterisation of , , BF4, and BF4
Parkin, Ivan P.,Woolins, J. Derek
, p. 925 - 930 (2007/10/02)
Reaction of 2Cl2, or SeCl4-Cl, with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia gives complexes of the type (ca. 70percent yield).Reaction of SeCl4 with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia produces in variable yield (ca. 24-74percent).Treatment of or with HBF4 in tetrahydrofuran-benzene produces BF4 or BF4 quantitatively according to 31P n.m.r., i.r., mass spectra, and microanalyses.Proton-exchange reactions reveal increasing basicity in the series ca. , , .
New Metal-Sulphur-Nitrogen Compounds from Reactions in Liquid Ammonia. The X-Ray Structures of trans-Bis(acetophenone dimethylhydrazone-Nα)-dichloropalladium(II) and 1N4>palladium(II)
O'Mahoney, Caroline A.,Parkin, Ivan P.,Williams, David J.,Woollins, J. Derek
, p. 1179 - 1186 (2007/10/02)
Reaction of Cl or Cl in liquid ammonia with or (L-L' = C-N ligand) gives and respectively; in some cases complexes containing S3N(1-) ligands were also obtained.An alternative route to complexes using is also reported.Reaction of S8-NH3(I) solutions with gives .The new complexes were characterised by microanalyses, i.r., n.m.r., and mass spectroscopy, and X-ray crystallography.
The Preparation and Crystal Structures of Platinum Stacking Compounds containing the S2N2H(-) Ligand: and
Jones, Ray,Kelly, Paul F.,Warrens, Christopher P.,Williams, David J.,Woollins, J. Derek
, p. 711 - 713 (2007/10/02)
Reaction of cis-PtCl2(PMe3)2 with 2 and in dichloromethane gives , (1), or alternatively protonation of yields , (2); the crystal structures of (1) and (2) reveal that the planar cations stack with significant close interactions.
