1042438-77-6

Basic information

• Product Name: methyl 2-O-benzyl-4-deoxy-6-O-trityl-α-D-xylo-hexopyranoside
• Synonyms: methyl 2-O-benzyl-4-deoxy-6-O-trityl-α-D-xylo-hexopyranoside
• CAS NO: 1042438-77-6
• Molecular Weight: 510.63
• Mol File: 1042438-77-6.mol

Chemical Properties

• CAS DataBase Reference: methyl 2-O-benzyl-4-deoxy-6-O-trityl-α-D-xylo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-O-benzyl-4-deoxy-6-O-trityl-α-D-xylo-hexopyranoside(1042438-77-6)
• EPA Substance Registry System: methyl 2-O-benzyl-4-deoxy-6-O-trityl-α-D-xylo-hexopyranoside(1042438-77-6)

Safety Data

• Hazardous Substances Data: 1042438-77-6(Hazardous Substances Data)

Upstream product

• 1042438-76-5 methyl 3-O-acetyl-2-O-benzyl-6-O-trityl-α-D-glucopyranoside 

Relevant articles and documents

Synthetic studies on the carbohydrate moiety of amipurimycin

The carbohydrate core of amipurimycin in its fully acetylated form was synthesized in 24 steps starting from commercially available methyl 4,6-O-benzylidene-α-D-glucopyranoside to give an overall yield of 1.5%. The late-stage intermediates involved were suitable for total synthesis of amipurimycin. It was further discovered that the branches and the protecting groups on the sugar rings of involved intermediates had a significant influence on their conformations, which in turn resulted in new and interesting cyclization reactions. Copyright Taylor & Francis Group, LLC.