104264-82-6

Upstream product

• 33581-77-0 trimethylsilyl [(trimethylsilyl)oxy]acetate 
• 97371-54-5 (-)-(2S,5R)-5-Methyl-2-(1-methyl-1-phenylethyl)cyclohexanon 

Downstream Products

• 108739-52-2 (3R,5S,6S,9R)-3-((R)-Hydroxy-phenyl-methyl)-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 108739-55-5 (3R,5S,6S,9R)-3-((S)-Hydroxy-phenyl-methyl)-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 108739-53-3 (3R,5S,6S,9R)-3-((R)-1-Hydroxy-butyl)-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 108739-56-6 (3R,5S,6S,9R)-3-((S)-1-Hydroxy-butyl)-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 104196-79-4 (3R,5S,6R,9S)-3-Benzyl-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 104196-79-4 (3R,5R,6R,9S)-3-Benzyl-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 104196-79-4 (3S,5R,6R,9S)-3-Benzyl-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 104196-78-3 (3R,5S,6R,9S)-3-Allyl-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 205057-17-6 (5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexanone 
• 108739-54-4 (3R,5S,6S,9R)-3-((R)-1-Hydroxy-2-methyl-propyl)-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 
• 108739-57-7 (3R,5S,6S,9R)-3-((S)-1-Hydroxy-2-methyl-propyl)-9-methyl-6-(1-methyl-1-phenyl-ethyl)-1,4-dioxa-spiro[4.5]decan-2-one 

Relevant academic research and scientific papers

Spiro Asymmetric Induction. Synthesis of Optically Pure α-Hydroxy Acid Derivatives by Alkylation of a Chiral Glycolate Enolate

The enolates of spiro-fused dioxolanones 4A and 4B serve as chiral glycolate enolate equivalents, providing either enantiomer of the α-substituted α-hydroxy esters 13 upon alkylation and hydrolysis