1042719-07-2Relevant academic research and scientific papers
Nitrogen-directed ortho-arylation and -heteroarylation of aromatic rings catalyzed by ruthenium complexes
Oi, Shuichi,Funayama, Raito,Hattori, Tetsutaro,Inoue, Yoshio
, p. 6051 - 6059 (2008/12/20)
The ruthenium-catalyzed direct ortho-arylation reactions of 2-phenylpyridine and 2-aryloxazolines have been successfully expanded to the direct aryl-heteroaryl coupling reactions using heteroaryl bromides. The reaction mechanism involving the RuII/RuIV intermediates is proposed from the results of the stoichiometric reaction of a divalent ruthenacycle complex of 2-phenylpyridine with bromobenzene.
