104315-82-4Relevant academic research and scientific papers
ORGANOALUMINUM-INDUCED ADDITION OF POLYHALOMETHANE TO OLEFINS
Maruoka, Keiji,Sano, Hiromi,Fukutani, Yoshimi,Yamamoto, Hisashi
, p. 1689 - 1692 (1985)
A mild procedure for the trimethylaluminum-induced addition of polyhalomethane to olefins has been described.
Study of Rhodamine-Based Fluorescent Probes for Organic Radical Intermediates
He, Jiaxin,Yan, Boyu,Meng, Jiangtao,Ran, Maogang,Zhou, Yutong,Deng, Jinfei,Li, Chao-Jun,Yao, Qiuli
supporting information, p. 4059 - 4064 (2021/05/17)
Rhodamine-based amide derivatives for the detection of radical intermediates in organic reactions were synthesized and used as fluorescent probes over a wide range of solvents. The mechanistic studies confirm a reversible opening and closing of the spirolactam ring. Compound 21 can be used to support the radical mechanism or in the real-time monitoring of radical intermediates.
Photo-induced atom-transfer radical reactions using charge-transfer complex between iodine and tertiary amine
Yoshioka, Eito,Kohtani, Shigeru,Hashimoto, Takurou,Takebe, Tomoko,Miyabe, Hideto
, p. 33 - 35 (2017/01/06)
In the presence of charge-transfer complexes between iodine and tertiary amines, the aqueous-medium atom-transfer radical reactions proceeded under visible light irradiation without the typical photocatalysts.
Effect of sodium acetate in atom transfer radical addition of polyhaloalkanes to olefins
Sawama, Yoshinari,Nakatani, Ryosuke,Imanishi, Takahiro,Fujiwara, Yuta,Monguchi, Yasunari,Sajiki, Hironao
, p. 8657 - 8660 (2014/03/21)
The atom transfer radical addition of polyhaloalkanes, such as bromotrichloromethane and polyfluoroalkyl iodine, to olefins smoothly proceeds in the presence of sodium acetate as an efficient auxiliary agent in dimethoxyethane. The present transition meta
The Fe0 promoted addition of CCl4 and CCl3Br to olefins
Bellesia, Franco,Forti, Luca,Ghelfi, Franco,Pagnoni, Ugo M.
, p. 961 - 971 (2007/10/03)
The radical addition of CCl4 or CCl3Br to olefins is efficiently promoted by iron filings in N,N-dimethylformamide under mild conditions.
Ruthenium(II)- and Rhenium(III)-catalysed Addition of Tetrahalogenomethanes to Alkenes and 1,ω-Dienes. Stereoselective Formation of cis-1,2-Disubstituted Cyclopentanes from 1,6-Dienes
Grigg, Ronald,Devlin, John,Ramasubbu, Ashok,Scott, Ronald M.,Stevenson, Paul
, p. 1515 - 1520 (2007/10/02)
Acetonitrile(trichloro)bis(triphenylphosphine)rhenium(III) is found to act as an initiator for the addition of carbon tetrachloride and bromotrichloromethane to terminal alkenes an dienes.Moderate to good yields of mono- and bis-adducts are obtained. 1,6-
