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CAS

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104319-03-1

R,R,R,R-{nickel(1,4,8,11-tetraazacyclotetradecane)}(2+) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 104319-03-1 Structure

  • Basic information

    1. Product Name: R,R,R,R-{nickel(1,4,8,11-tetraazacyclotetradecane)}(2+)
    2. Synonyms:
    3. CAS NO:104319-03-1
    4. Molecular Formula:
    5. Molecular Weight: 259.017
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 104319-03-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: R,R,R,R-{nickel(1,4,8,11-tetraazacyclotetradecane)}(2+)(CAS DataBase Reference)
    10. NIST Chemistry Reference: R,R,R,R-{nickel(1,4,8,11-tetraazacyclotetradecane)}(2+)(104319-03-1)
    11. EPA Substance Registry System: R,R,R,R-{nickel(1,4,8,11-tetraazacyclotetradecane)}(2+)(104319-03-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 104319-03-1(Hazardous Substances Data)

104319-03-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 104319-03-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,4,3,1 and 9 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 104319-03:
(8*1)+(7*0)+(6*4)+(5*3)+(4*1)+(3*9)+(2*0)+(1*3)=81
81 % 10 = 1
So 104319-03-1 is a valid CAS Registry Number.

104319-03-1Relevant articles and documents

Formation and homolysis of organonickel(III) complexes

Kelley, Dougles G.,Marchaj, Adam,Bakac, Andreja,Espenson, James H.

, p. 7583 - 7587 (1991)

The reactions of Ni(1,4,8,11-tetraazacyclotetradecane)2+ with alkyl radicals were studied. Data were collected for the R,R,S,S (or β) and R,R,R,R (or α) isomers. The reactions form σ -bonded organometalllc cations, as in the equation NIL2+

Stabilization of the monovalent nickel complex with 1,4,8,11-tetraazacyclotetradecane in aqueous solutions by N- and C-methylation. An electrochemical and pulse radiolysis study

Jubran, Nusrallah,Ginzburg, Gregory,Cohen, Haim,Koresh, Yaacov,Meyerstein, Dan

, p. 251 - 258 (2008/10/08)

The divalent nickel complexes with 1,4,8,11-tetraazacyclotetradecane (L1), 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (L2), meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L3), and 1,4,5,7,7,8,11,12,14,14-decamethyl-1,4,8,11-tetraazacyclotetradecane (L4) were reduced by reactions with eaq- and CO2-? and by electrochemical reactions in aqueous solutions. The redox potentials of the NiLi2+/NiLi+ couples are -1.58, -1.15, -1.42, and -0.98 V vs. SCE for i = 1, 2, 3, and 4, respectively. The UV absorption bands of NiLi+ are attributed to CTTS transitions. The kinetics of reduction of Co(NH3)63+, Ru(NH3)63+, O2, and N2O by NiLi+ are reported and discussed. The self-exchange rates of reaction between NiLi+ and NiLi2+ were calculated by using the Marcus cross relation. The EPR spectra of NiL2+ and NiL4+ are reported. The complexation of NiLi2+ by OH- was studied. The results are discussed in detail. NiL2+ and NiL4+ are suggested as new, powerful, easily attainable single-electron-reducing agents that can be used over a wide pH range in aqueous solutions.

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