10433-29-1Relevant academic research and scientific papers
HIGHLY REGIOSELECTIVE RING OPENING OF EPOXIDES WITH ALCOHOLS CATALYZED BY ORGANOTIN PHOSPHATE CONDENSATES
Otera, Junzo,Yoshinaga, Yukari,Hirakawa, Kazuhisa,Nakata, Tetsuya
, p. 3219 - 3222 (1985)
Organotin phosphate condensates proved to catalyze the ring opening reaction of epoxides with alcohols in a highly regioselective manner.
EFFICIENT CATALYSIS OF HETEROPOLY ACID FOR ALCOHOLYSIS OF EPOXIDE
Izumi, Yusuke,Hayashi, Kyoji
, p. 787 - 790 (1980)
Heteropoly acid (HPA) was found to catalyze the alcoholysis of epoxide more efficiently than the conventional acid catalysts such as sulfuric acid, perchloric acid and p-toluenesulfonic acid, at 45 deg C in the homogeneous liquid phase.The reason for the high catalytic activity of HPA is also discussed.
Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol and properties of products obtained
Kerimov,Orudzheva,Mamedova,Alieva
, p. 1364 - 1369 (2014/01/06)
Ionic telomerization of 1-chloro-2,3-epoxypropane with allyl alcohol in the presence of boron trifluoride etherate as a route to halogenated epoxy oligoethers was studied. Selective chlorination or bromination of the intermediate oligo(chlorohydrin), followed by dehydrochlorination (epoxidation) of the intermediate oligohalohydrins with NaOH, was performed. The synthesized products are effi cient as active diluents for a compound based on ED-20 resin.
