10438-97-8

Basic information

• Product Name: Crinan-3β-ol
• Synonyms: Crinan-3β-ol;Dihydrocrinine
• CAS NO: 10438-97-8
• Molecular Formula: C16H19NO3
• Molecular Weight: 273.32696
• Mol File: 10438-97-8.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Crinan-3β-ol(CAS DataBase Reference)
• NIST Chemistry Reference: Crinan-3β-ol(10438-97-8)
• EPA Substance Registry System: Crinan-3β-ol(10438-97-8)

Safety Data

• Hazardous Substances Data: 10438-97-8(Hazardous Substances Data)

Upstream product

• 33531-75-8 3a-benzo[1,3]dioxol-5-yl-1-benzyl-(3ar,7ac)-octahydro-indol-6t-ol 
• 32209-88-4 3a-benzo[1,3]dioxol-5-yl-1-benzyl-(3ar,7ac)-octahydro-indol-6-one 
• 50-00-0 formaldehyd 
• 114047-13-1 (3aS*,6S*,7aS*)-6-acetoxy-3a,4,5,6,7,7a-hexahydro-3a-(3',4'-methylenedioxyphenyl)indoline 
• 32209-89-5 cis-6-hydroxy-3a-(3,4-methylenedioxyphenyl)-2,3,3a,4,5,6,7,7a-octahydro-1H-indole 
• 33531-75-8 3a-benzo[1,3]dioxol-5-yl-1-benzyl-(3ar,7ac)-octahydro-indol-6c-ol 
• 114047-13-1 (3aS*,6R*,7aS*)-6-acetoxy-3a,4,5,6,7,7a-hexahydro-3a-(3',4'-methylenedioxyphenyl)indoline 
• 33531-78-1 (3aR^*,6R^*,7aS^*)-3a-(1,3-benzodioxol-5-yl)octahydroindole-6-ol 
• 4439-02-5 3,4-methylenedioxyphenylacetonitrile 
• 148614-09-9 (Z)-2-(3,4-methylenedioxyphenyl)-6-trimethylsilyl-5-hexenenitrile 
• 148614-10-2 (Z)-2-(chloroethyl)-2-(3,4-methylenedioxyphenyl)-6-trimethylsilyl-5-hexenenitrile 
• 96400-90-7 4-Benzo[1,3]dioxol-5-yl-4-((Z)-4-trimethylsilanyl-but-3-enyl)-3,4-dihydro-2H-pyrrole 
• 96400-93-0 cis-3a-(3,4-methylenedioxyphenyl)-2,3,3a,4,5,7a-hexahydro-1H-indole 
• 7700-86-9 (+/-)-oxo-crinine 

Relevant articles and documents

Bioinspired enantioselective synthesis of crinine-type alkaloids: Via iridium-catalyzed asymmetric hydrogenation of enones

A bioinspired enantioselective synthesis of crinine-type alkaloids has been developed by iridium-catalyzed asymmetric hydrogenation of racemic cycloenones. The method features a biomimetic stereodivergent resolution of the substrates bearing a remote arylated quaternary stereocenter. Using this protocol, 24 crinine-type alkaloids and 8 analogues were synthesized in a concise and rapid way with high yield and high enantioselectivity.

Synthesis of Sceletium and Amaryllidaceae Alkaloids, (+/-)-Mesembrine and (+/-)-Dihydromaritidine, (+/-)-Epidihydromaritidine, (+/-)-Elwesine, and (+/-)-Epielwesine

The alkylation of 2-arylcyclohexanones (12b and 6) with alkyl halides or acrylonitrile and 50percent aq. sodium hydroxide in the presence of a phase-transfer catalyst (18-crown-6) was found to give readily 2-alkyl-2-arylcyclohexanones (14 and 16) in fair

The total synthesis of dihydrocrinine and related compounds.

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