1043904-29-5

Basic information

• Product Name: (μ1,5-dicyanamidate)(2-pyridinecarboxaldehyde benzoyl hydrazonate)copper(II)
• CAS NO: 1043904-29-5
• Molecular Weight: 353.83
• Mol File: 1043904-29-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (μ1,5-dicyanamidate)(2-pyridinecarboxaldehyde benzoyl hydrazonate)copper(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (μ1,5-dicyanamidate)(2-pyridinecarboxaldehyde benzoyl hydrazonate)copper(II)(1043904-29-5)
• EPA Substance Registry System: (μ1,5-dicyanamidate)(2-pyridinecarboxaldehyde benzoyl hydrazonate)copper(II)(1043904-29-5)

Safety Data

• Hazardous Substances Data: 1043904-29-5(Hazardous Substances Data)

Upstream product

• 504-66-5 dicyandiamide 

Relevant articles and documents

Two new pseudohalide-bridged Cu(II) complexes with a hydrazone ligand: Syntheses, crystal structures and magnetic studies

Two new pseudohalide-bridged copper(II) complexes [{Cu(PBH)(μ1,1-CNO)}2] (1) and {Cu(PBH)(μ1,5-NCNCN)}n (2) (where HPBH = 2-pyridinecarboxaldehyde benzoyl hydrazone) have been synthesised and characterised by elemental analysis, CV, IR and UV-Vis spectral studies. The tridentate hydrazone pro-ligand (HPBH) was obtained by the condensation of benzhydrazide and pyridine-2-carboxaldehyde. Structures of both complexes have been established by X-ray crystallography which shows that 1 is a μ1,1-CNO--bridged dimer whereas 2 is a μ1,5-dca-bridged (dca = dicyanamide) linear polynuclear structure. Variable temperature magnetic susceptibility studies indicate weak antiferromagnetic interactions with J values -0.50 cm-1 and -0.10 cm-1 for 1 and 2, respectively.