1044148-86-8Relevant academic research and scientific papers
Asymmetric auto-tandem catalysis with a planar-chiral ruthenium complex: Sequential allylic amidation and atom-transfer radical cyclization
Kanbayashi, Naoya,Takenaka, Kazuhiro,Okamura, Taka-Aki,Onitsuka, Kiyotaka
, p. 4897 - 4901 (2013)
Ru does it all: A novel example of an asymmetric auto-tandem reaction catalyzed by a planar-chiral cyclopentadienyl-ruthenium complex is described. The reaction of allylic chloride with α-haloamides provides synthetically useful, diastereomerically and enantiomerically enriched γ-lactams with multiple stereogenic centers through one-pot sequential allylic amidation/atom-transfer radical cyclization. PG=protecting group. Copyright
Aldehyde selective Wacker oxidations of phthalimide protected allylic amines: A new catalytic route to β3-amino acids
Weiner, Barbara,Baeza, Alejandro,Jerphagnon, Thomas,Feringa, Ben L.
supporting information; experimental part, p. 9473 - 9474 (2009/12/06)
(Chemical Equation Presented) A new method for the synthesis of β3-amino acids is presented. Phthalimide protected allylic amines are oxidized under Wacker conditions selectively to aldehydes using PdCl2 and CuCl or Pd(MeCN)2/s
Application of iridium catalyzed allylic substitution reactions in the synthesis of branched tryptamines and homologues via tandem hydroformylation- Fischer indole synthesis
Bondzic, Bojan P.,Farwick, Andreas,Liebich, Jens,Eilbracht, Peter
supporting information; experimental part, p. 3723 - 3731 (2009/02/05)
Combination of enantioselective allylation reactions with a tandem hydroformylation-Fischer indole synthesis sequence as a highly diversity-oriented strategy for the synthesis of tryptamines and homologues was explored. This modular approach allows the su
