104416-22-0Relevant academic research and scientific papers
HIGHLY STEREOSELECTIVE APPROACH TO CHIRAL BUILDING BLOCK POSSESSING THREE CONTIGUOUS ASYMMETRIC CENTERS. PREPARATION OF FOUR POSSIBLE DIASTEREOMERS OF β,β'-DIMETHYL-BIS-HOMOALLYLIC ALCOHOL DERIVATIVE
Suzuki, Keisuke,Katayama, Eiji,Tomooka, Katsuhiko,Matsumoto, Takashi,Tsuchihashi, Gen-ichi
, p. 3707 - 3710 (2007/10/02)
All four diastereomers of chiral alcohol 2 with three contiguous chiral centers were stereoselectively prepared via diastereoselective addition of nucleophiles (crotyl metal or H(1-)) to α-methyl-β,γ-unsaturated carbonyl compounds 1.
