104449-63-0Relevant academic research and scientific papers
DIASTEREOSELECTIVE NaBH4 REDUCTIONS OF (dl) α-KETO ESTERS
Ben Hassine, B.,Gorsane, M.,Pecher, J.,Martin, R.H.
, p. 597 - 604 (2007/10/02)
The (dl) α-keto esters 16, were prepared from the (dl) carbinols 1 to 4 and from (dl)-2-hydroxyheptahelicene 5.These (dl) α-keto esters underwent NaBH4 reductions to give the corresponding diastereomeric (dl) α-hydroxy esters 17, with 54 to c.a.100percent diastereomeric excesses.
