1044502-89-7Relevant academic research and scientific papers
Microwave-promoted hydrogenation and alkynylation reactions with palladium-loaded multi-walled carbon nanotubes
Olivier, Jean-Hubert,Camerel, Franck,Ziessel, Raymond,Retailleau, Pascal,Amadou, Julien,Pham-Huu, Cuong
, p. 920 - 924 (2008/12/20)
Multi-walled carbon nanotubes loaded with Pd(0) clusters (average size distribution 9 nm) have been used under microwave irradiation as catalysts in hydrogenation and alkynylation reactions under "eco-friendly" conditions; reduced cinnamic esters and cross-coupled products were obtained in good yields; use of piperidine as the base provided, in a regiospecific process, novel doubly alkynylated compounds unambiguously characterized by NMR correlation experiments and X-ray diffraction. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
