104469-69-4

Basic information

• Product Name: Mn(CO)2(P(C₆H₁₁)3)(C₄H₄N)
• CAS NO: 104469-69-4
• Molecular Weight: 457.475
• Mol File: 104469-69-4.mol

Chemical Properties

• CAS DataBase Reference: Mn(CO)2(P(C₆H₁₁)3)(C₄H₄N)(CAS DataBase Reference)
• NIST Chemistry Reference: Mn(CO)2(P(C₆H₁₁)3)(C₄H₄N)(104469-69-4)
• EPA Substance Registry System: Mn(CO)2(P(C₆H₁₁)3)(C₄H₄N)(104469-69-4)

Safety Data

• Hazardous Substances Data: 104469-69-4(Hazardous Substances Data)

Upstream product

• 32761-36-7 (η5-pyrrolyl)tricarbonylmanganese(I) 
• 2622-14-2 tricyclohexylphosphine 

Relevant articles and documents

SYNTHESES AND CARBON MONOXIDE SUBSTITUTION REACTIONS OF η5-N-HETEROCYCLE MANGANESE TRICARBONYLS

A new method of synthesis of η5-pyrrolyltricarbonylmanganese(I) is reported, along with the first syntheses of η5-indolyltricarbonylmanganese(I) and of η5-1-pyrindinyltricarbonylmanganese(I).Kinetic studies on CO substitution reactions of these η5-N-heterocyclic manganese carbonyls show that the reactions take place by a second-order process, first-order in metal complex and first-order in nucleophile.The most significant observation is that the N-heterocyclic compounds react faster than do their carbocyclic counterparts.This anticipated result is consistent with the greater electron-withdrawing ability of the N systems in the transition state for reaction, because N is more electronegative than is C.