1044761-94-5Relevant articles and documents
Isocyanide-promoted ylidene transfer to phosphorus: Rearrangement in the first-generation grubbs complex
Galan, Brandon R.,Pitak, Mateusz,Keister, Jerome B.,Diver, Steven T.
, p. 3630 - 3632 (2008)
Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexy-lphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; aprobable mechanism for the ligand-promoted transformation is also discussed.