1044810-08-3

Upstream product

• 609-09-6 Diethyl ketomalonate 
• 716377-12-7 benzyl 2-acetamido-2,3-dideoxy-4,6-O-isopropylidene-3-C-(penta-2',4'-dienyl)-α-D-glucopyranoside 

Downstream Products

• 1044810-14-1 benzyl 2-acetamido-2,3-dideoxy-3-C-(ethyl 2',3',4'-trideoxy-α-L-glycero-hex-2'-enopyranosyluronate)methyl-4,6-O-isopropylidene-α-D-glucopyranoside 
• 1044810-16-3 benzyl 2-acetamido-2,3-dideoxy-3-C-(ethyl 2',3',4'-trideoxy-β-D-glycero-hex-2'-enopyranosyluronate)methyl-4,6-O-isopropylidene-α-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis of C-disaccharides via a hetero-Diels-Alder reaction and further stereocontrolled transformations

The partial de novo synthesis of two new C-disaccharides containing d-glucosamine is described. The strategy is based on a hetero-Diels-Alder reaction leading to a 1:1 mixture of separable cycloadducts, which have been stereoselectively functionalized and converted into α-d-Galp-(1→3)-C-d-GlcpNAc and α-l-Galp-(1→3)-C-d-GlcpNAc.