104483-32-1Relevant academic research and scientific papers
A Convenient New Route to 1-Haloalkyl Carbonates
Senet, Jean-Pierre,Sennyey, Gerard,Wooden, Gary P.
, p. 407 - 410 (2007/10/02)
Alkyl (or alkenyl or aryl) 1-haloalkyl carbonates are conveniently prepared by reaction of an aldehyde with an alkyl (or alkenyl or aryl) carbonohalidate (haloformate) in the presence of a catalyst.
NOVEL CHLORIDE TO BROMIDE EXCHANGE: PREPARATION OF 1-BROMOALKYL CARBONATES
Senet, Jean-Pierre,Sennyey, Gerard,Wooden, Gary P.
, p. 1525 - 1530 (2007/10/02)
A new method is described for the synthesis of 1-bromoalkyl carbonates which consists of reacting the corresponding 1-chloroalkyl carbonate with a volatile electrophilic bromine containing reagent (E-Br) and a catalyst.The equilibrium is driven to product by removal of the E-Cl formed.
Process for the preparation of 1-bromoethyl hydrocarbonyl carbonates and new 1-bromoethyl hydrocarbonyl carbonates
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, (2008/06/13)
The invention relates to a process for the preparation of 1-bromoethyl hydrocarbonyl carbonates, characterized in that anhydrous hydrobromic acid is reacted with a vinyl hydrocarbonyl carbonate of formula STR1 in which R denotes a saturated, substituted or unsubstituted C1 -C12 aliphatic radical or C5 -C24 alicyclic radical, or a substituted or unsubstituted aromatic radical, at a temperature between 10° and 100° C. The invention also relates to the new 1-bromoethyl hydrocarbonyl carbonates of formula: STR2 These carbonates are particularly sought after for introducing a carbonate group into a molecule.
