104486-85-3

Upstream product

• 104486-83-1 syn-(5R,6R)-5,6-Dimethyl-5,6-dihydropyran-2-one 
• 104431-99-4 (S)-((2R,4R,5R,6R)-4-[1,3]Dithiolan-2-yl-2-methoxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-hydroxy-acetic acid methyl ester 
• 104431-99-4 ((2R,4R,5R,6R)-4-[1,3]Dithiolan-2-yl-2-methoxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-hydroxy-acetic acid methyl ester 
• 88635-99-8 (R)-3-((S)-3-Hydroxy-2-methyl-butyryl)-4-isopropyl-oxazolidin-2-one 
• 104431-97-2 (-)-(3R,4R,5R)-4,5-dimethyl-3-(1,3-dithiolan-2-yl)pentanolide 
• 104431-95-0 (4S,5R,6R)-5,6-Dimethyl-4-nitromethyl-tetrahydro-pyran-2-one 
• 65781-37-5 (2S,3R)-2-Methyl-3-(tetrahydro-pyran-2-yloxy)-butyraldehyde 
• 104486-84-2 (-)-(1R,2R,6R,7R)-6,7-dimethyl-3-oxo-2,8-dioxabicyclo[3.3.0]octane 
• 104431-96-1 (3aS,4R,5R,6aS)-4,5-Dimethyl-tetrahydro-furo[2,3-b]furan-2-one 
• 104432-00-0 Benzoic acid (S)-((2R,4R,5R,6R)-4-[1,3]dithiolan-2-yl-2-methoxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-methoxycarbonyl-methyl ester 
• 110134-92-4 Benzoic acid (S)-((2R,4R,5R,6R)-4-formyl-2-methoxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-methoxycarbonyl-methyl ester 
• 104432-01-1 Benzoic acid (S)-((2R,4R,5R,6R)-4-hydroxymethyl-2-methoxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-methoxycarbonyl-methyl ester 
• 110134-91-3 ((2R,4R,5R,6R)-4-[1,3]Dithiolan-2-yl-2-hydroxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-(1-methoxy-1-methyl-ethoxy)-acetic acid methyl ester 
• 104431-98-3 ((2R,4R,5R,6R)-4-[1,3]Dithiolan-2-yl-2-methoxy-5,6-dimethyl-tetrahydro-pyran-2-yl)-oxo-acetic acid methyl ester 

Downstream Products

• 123364-05-6 (S)-Acetoxy-((2R,4R,5R,6R)-2-methoxy-5,6-dimethyl-4-phenylselanylmethyl-tetrahydro-pyran-2-yl)-acetic acid; compound with dicyclohexyl-amine 

Relevant academic research and scientific papers

STEREOCONTROLLED TOTAL SYNTHESIS OF (+)-PEDERINE

A mild one-pot method for the synthesis of acyclic N-(1-methoxyalkyl)amides starting from carboxylic acid and methyl imidates has been developed and applied to the first total synthesis of (+)-pederine (1), a potent insect poison.Furthermore, the stereocontrolled total synthesis of 1 was also achieved by employing acid catalyzed double alkoxy-exchange reaction of N-(1-methoxyalkyl)amide group as key step.